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Molten Salt Techniques: Volume 2

Editat de Robert J. Gale, D.G. Lovering
en Limba Engleză Paperback – 24 oct 2013
This second volume carries on the excellent work of its predecessor, ex­ tending its scope to other melts and to other techniques. It continues to present first-hand understanding and experience of this difficult and demanding field. There is ever present the trade-off or reconciliation between the novel chemistry of systems not dominated by the mediating influence of a supposedly indifferent solvent and the high temperatures required to effect the fluidity of the system. At the limit, the very high temperatures so increase the rates of all reactions as to dissolve the temporal difference between the thermodynamic and the kinetic view of chemistry. What can happen will happen and invariably does happen. Vessels corrode, the apparatus becomes a reactant, and the number of tolerant materials able to withstand the attack shrinks to graphite, boron carbide or, if all else fails, to frozen parts of the molten salt itself. It is probably true that there is no limit to man's ingenuity but I believe that God gave us molten salts just to test that thesis. If there is ever a Molten Salt Club, and Englishmen love clubs, its membership will be exclusive. It would certainly include the authors of this series. Graham Hills University of Strathclyde ix Preface In the first volume of this series, we expressed our contention that a real need existed for practical guidance in the field of molten salt experimentation.
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Specificații

ISBN-13: 9781461575047
ISBN-10: 1461575044
Pagini: 276
Ilustrații: XVIII, 257 p. 45 illus.
Dimensiuni: 152 x 229 x 14 mm
Greutate: 0.37 kg
Ediția:Softcover reprint of the original 1st ed. 1984
Editura: Springer Us
Colecția Springer
Locul publicării:New York, NY, United States

Public țintă

Research

Cuprins

1. Introduction.- References.- 2. Actinides.- 1. Introduction.- 2. Special Enclosures Required for Actinides.- 3. Materials Problems.- 4. Microtechniques.- 5. Techniques for Purification of Multigram Quantities of Actinides and Their Salts.- 6. Metal Preparation and Purification.- 7. Physical Properties Measurements.- 8. Absorption Spectra.- 9. Electrochemistry.- 10. Summary.- References.- 3. Cryolite Systems.- 1. Introduction.- 2. Container Materials.- 3. Preparative Techniques.- 4. The Study of Thermodynamic and Physicochemical Properties.- 5. Electrodes in Molten Cryolite.- 6. Spectroscopy in Molten Cryolite.- 7. Miscellaneous Techniques.- 8. Conclusion.- References.- 4. Reference Electrodes for Molten Electrolytes.- 1. Introduction.- 2. Theoretical Principles.- 3. Principles of Reference Electrode Construction and Application.- 4. Description of Reference Electrodes.- References.- 5. Neutron Diffraction.- 1. Introduction.- 2. Molten Salt Structure.- 3. Neutron or X-Ray Diffraction.- 4. Samples Amenable to Neutron Diffraction Study.- 5. Sample Preparation.- 6. Sample Containers.- 7. Furnaces.- 8. Neutron Beam Facilities.- 9. Data Analysis.- 10. Melts Studied Using Neutron Diffraction.- 11. Summary.- References.- 6. Dry Boxes and Inert Atmosphere Techniques.- 1. Introduction.- 2. Equipment.- 3. Operation.- 4. Common Operations Conducted inside Dry Boxes.- References.