Introduction to Coordination Chemistry
Autor Lawranceen Limba Engleză Paperback – 4 feb 2010
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Specificații
ISBN-13: 9780470519318
ISBN-10: 0470519312
Pagini: 306
Ilustrații: black & white illustrations, black & white tables, figures
Dimensiuni: 189 x 246 x 17 mm
Greutate: 0.6 kg
Editura: Wiley
Locul publicării:Chichester, United Kingdom
ISBN-10: 0470519312
Pagini: 306
Ilustrații: black & white illustrations, black & white tables, figures
Dimensiuni: 189 x 246 x 17 mm
Greutate: 0.6 kg
Editura: Wiley
Locul publicării:Chichester, United Kingdom
Public țintă
2 nd/3 rd year chemistry undergraduates, final year inorganic students and postgraduates, research scientists in other fields that draw on aspects of metal molecule interactionsNotă biografică
Professor Geoffrey Lawrance; Professor of Chemistry and Assistant Dean Research (Science & IT), The University of Newcastle, Australia
Professor Lawrance is the author or co-author of over 290 journal articles, review articles and book chapters in a career spanning three decades. He has contributed chapters to Encyclopaedia of Inorganic Chemistry II (Wiley, 2005), and Comprehensive Coordination Chemistry II (Elsevier, 2004).
Professor Lawrance is the author or co-author of over 290 journal articles, review articles and book chapters in a career spanning three decades. He has contributed chapters to Encyclopaedia of Inorganic Chemistry II (Wiley, 2005), and Comprehensive Coordination Chemistry II (Elsevier, 2004).
Cuprins
PrefacePreamble
1 The Central Atom
1.1 Key Concepts in Coordination Chemistry
1.2 A Who's Who of Metal Ions
1.3 Metals in Molecules
1.4 The Road Ahead
Concept Keys
Further Reading
2 Ligands
2.1 Membership: Being a Ligand
2.2 Monodentate Ligands - The Simple Type
2.3 Greed is Good - Polydentate Ligands
2.4 Polynucleating Species - Molecular Bigamists
2.5 A Separate Race - Organometallic Species
Concept Keys
Further Reading
3 Complexes
3.1 The Central Metal Ion
3.2 Metal-Ligand Marriage
3.3 Holding On - The Nature of Bonding in Metal Complexes
3.4 Coupling - Polymetallic Complexes
3.5 Making Choices
3.6 Complexation Consequences
Concept Keys
Further Reading
4 Shape
4.1 Getting in Shape
4.2 Forms of Complex Life
4.3 Influencing Shape
4.4 Isomerism - Real 3D Effects
4.5 Sophisticated Shapes
4.6 Defining Shape
Concept Keys
Further Reading
5 Stability
5.1 The Makings of a Stable Relationship
5.2 Complexation - Will it Last?
5.3 Reactions
Concept Keys
Further Reading
6 Synthesis
6.1 Molecular Creation - Ways to Make Complexes
6.2 Core Metal Chemistry - Periodic Table Influences
6.3 Reactions Involving the Coordination Shell
6.4 Reactions Involving the Metal Oxidation State
6.5 Reactions Involving Coordinated
6.6 Organometallic Synthesis
Concept Keys
Further Reading
7 Properties
7.1 Finding Ways to Make Complexes Talk - Investigative Methods
7.2 Getting Physical - Methods and Outcomes
7.3 Probing the Life of Complexes - Using Physical Methods
Concept Keys
Further Reading
8 A Complex Life
8.1 Life's a Metal Ion
8.2 Metalloproteins and Metalloenzymes
8.3 Doing What Comes Unnaturally
8.4 A Laboratory-free Approach - In Silico Prediction
Concept Keys
Further Reading
9 Complexes and Commerce
9.1 Kill or Cure? - Complexes as Drugs
9.2 How Much? - Analysing with Complexes
9.3 Profiting from Complexation
9.4 Being Green
9.5 Complex Futures
Concept Keys
Further Reading
Appendix One Nomenclature
Appendix Two Molecular Symmetry: The Point Group
Index
1 The Central Atom
1.1 Key Concepts in Coordination Chemistry
1.2 A Who's Who of Metal Ions
1.3 Metals in Molecules
1.4 The Road Ahead
Concept Keys
Further Reading
2 Ligands
2.1 Membership: Being a Ligand
2.2 Monodentate Ligands - The Simple Type
2.3 Greed is Good - Polydentate Ligands
2.4 Polynucleating Species - Molecular Bigamists
2.5 A Separate Race - Organometallic Species
Concept Keys
Further Reading
3 Complexes
3.1 The Central Metal Ion
3.2 Metal-Ligand Marriage
3.3 Holding On - The Nature of Bonding in Metal Complexes
3.4 Coupling - Polymetallic Complexes
3.5 Making Choices
3.6 Complexation Consequences
Concept Keys
Further Reading
4 Shape
4.1 Getting in Shape
4.2 Forms of Complex Life
4.3 Influencing Shape
4.4 Isomerism - Real 3D Effects
4.5 Sophisticated Shapes
4.6 Defining Shape
Concept Keys
Further Reading
5 Stability
5.1 The Makings of a Stable Relationship
5.2 Complexation - Will it Last?
5.3 Reactions
Concept Keys
Further Reading
6 Synthesis
6.1 Molecular Creation - Ways to Make Complexes
6.2 Core Metal Chemistry - Periodic Table Influences
6.3 Reactions Involving the Coordination Shell
6.4 Reactions Involving the Metal Oxidation State
6.5 Reactions Involving Coordinated
6.6 Organometallic Synthesis
Concept Keys
Further Reading
7 Properties
7.1 Finding Ways to Make Complexes Talk - Investigative Methods
7.2 Getting Physical - Methods and Outcomes
7.3 Probing the Life of Complexes - Using Physical Methods
Concept Keys
Further Reading
8 A Complex Life
8.1 Life's a Metal Ion
8.2 Metalloproteins and Metalloenzymes
8.3 Doing What Comes Unnaturally
8.4 A Laboratory-free Approach - In Silico Prediction
Concept Keys
Further Reading
9 Complexes and Commerce
9.1 Kill or Cure? - Complexes as Drugs
9.2 How Much? - Analysing with Complexes
9.3 Profiting from Complexation
9.4 Being Green
9.5 Complex Futures
Concept Keys
Further Reading
Appendix One Nomenclature
Appendix Two Molecular Symmetry: The Point Group
Index
Descriere
Introduction to Coordination Chemistry examines and explains how metals and molecules that bind as ligands interact, and the consequences of this assembly process. This book describes the chemical and physical properties and behavior of the complex assemblies that form, and applications that may arise as a result of these properties.