Table of Contents- Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation- Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds- Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus- Remote C–H Activation via Through-Space Palladium and Rhodium Migrations- Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation- Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins- Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages- Rhodium-Catalyzed C–H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds- Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion- Metal-Catalyzed Oxidations of C–H to C–N Bonds