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Advanced Organic Chemistry de Francis A. Carey

Advanced Organic Chemistry: Advanced Organic Chemistry

Autor Francis A. Carey, Richard J. Sundberg
en Limba Engleză Paperback – 6 sep 2007

Observăm că Advanced Organic Chemistry își păstrează statutul de resursă fundamentală pentru studiile avansate, punând accent pe aplicabilitatea practică a sintezei organice în cercetarea modernă. Această a cincea ediție a fost recalibrată pentru a oferi studenților și cercetătorilor instrumentele necesare interpretării literaturii de specialitate, integrând progrese recente, în special în domeniul chimiei computaționale. Structura volumului este una progresivă, pornind de la metode de formare a legăturilor carbon-carbon prin intermediul nucleofililor de carbon și continuând cu transformări complexe ale grupelor funcționale, adiții electrofile și reduceri. Credem că organizarea tematică — ce acoperă de la compușii organometalici din grupele I și II până la reacții care implică metale de tranziție și bor, siliciu sau staniu — permite o înțelegere profundă a mecanismelor de reacție. Cititorii familiarizați cu Organic Synthesis de Michael Smith vor aprecia la volumul de față abordarea mai analitică și fundamentarea riguroasă pe literatura primară de cercetare, transformând textul dintr-un simplu manual într-un ghid de referință pentru laborator. Merită menționat că, deși trece în revistă conceptele fundamentale, volumul solicită o bază solidă de cunoștințe prealabile, fiind conceput pentru a face tranziția de la cursurile introductive la rigoarea investigației științifice autonome. Prezența modelelor digitale pe site-ul însoțitor completează experiența de studiu, oferind suport vizual pentru structurile și selectivitatea reacțiilor descrise în cele peste 1300 de pagini.

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Specificații

ISBN-13: 9780387683546
ISBN-10: 0387683542
Pagini: 1321
Ilustrații: XXX, 1321 p.
Dimensiuni: 255 x 187 x 50 mm
Greutate: 2.35 kg
Ediția:Fifth Edition 2007
Editura: SPRINGER VERLAG NEW YORK INC
Colecția Advanced Organic Chemistry
Seria Advanced Organic Chemistry

Locul publicării:New York, NY, United States

Public țintă

Graduate

De ce să citești această carte

Recomandăm acest volum studenților la masterat și doctorat care doresc să stăpânească tehnicile de sinteză organică. Prin consultarea acestui manual, cititorul câștigă capacitatea de a naviga prin literatura de cercetare și de a proiecta rute de sinteză complexe. Este resursa definitivă pentru cei care au nevoie de o bază teoretică solidă susținută de date experimentale concrete și referințe bibliografice actualizate.

Despre autor

Francis A. Carey este un distins profesor emerit al University of Virginia, cu o carieră academică impresionantă începută în 1966. Educat la Drexel University și Penn State, acesta a contribuit semnificativ la domeniul chimiei organice prin publicarea a peste patruzeci de lucrări de cercetare axate pe mecanisme sintetice. Experiența sa pedagogică de zeci de ani în predarea cursurilor de chimie organică se reflectă în claritatea și structura riguroasă a acestui tratat, considerat un standard de aur în educația chimică universitară.

Cuprins

Alkylation of Enolates and Other Carbon Nucleophiles.- Reactions of Carbon Nucleophiles with Carbonyl Compounds.- Functional Group Interconversion by Substitution, Including Protection and Deprotection.- Electrophilic Additions to Carbon-Carbon Multiple Bonds.- Reduction of Carbon-Carbon Multiple Bonds, Carbonyl Groups, and Other Functional Groups.- Concerted Cycloadditions, Unimolecular Rearrangements, and Thermal Eliminations.- Organometallic Compounds of Group I and II Metals.- Reactions Involving Transition Metals.- Carbon-Carbon Bond-Forming Reactions of Compounds of Boron, Silicon, and Tin.- Reactions Involving Carbocations, Carbenes, and Radicals as Reactive Intermediates.- Aromatic Substitution Reactions.- Oxidations.- Multistep Syntheses.

Recenzii

From the reviews of the fifth edition:
"Advanced Organic Chemistry … the well-known textbook for graduate students – has now appeared in a 5th edition. … Carey & Sundberg will be interesting to all students who seek a detailed understanding of organic chemistry, and who wish to refresh and embellish their existing knowledge. On the strength of the scope and quality of the explanations, this pair of texts is recommended for use as the resource of first resort for specific research questions in one’s later career." (www.organische-chemie.ch, January, 2008)

Notă biografică

Francis A. Carey is a native of Pennsylvania, educated in the public schools of Philadelphia, at Drexel University (B.S. in chemistry, 1959), and at Penn State (Ph.D. 1963). Following postdoctoral work at Harvard and military service, he was appointed to the chemistry faculty of the University of Virginia in 1966. Prior to retiring in 2000, he regularly taught the two-semester lecture courses in general chemistry and organic chemistry. With his students, Professor Carey has published over forty research papers in synthetic and mechanistic organic chemistry.

 
Professor Sundberg is primarily engaged in teaching and chemical education. Along with Francis A. Carey he is the author of “Advanced Organic Chemistry. Professor Sundberg is also interested in synthetic methodology in heterocyclic chemistry and is the author of “Indoles” in the Best Synthetic Methods Series (Academic Press, 1996).
 
 

Caracteristici

Parts A and B may stand alone; together, they provide a comprehensive foundation for study in organic chemistryUpdated material reflecting scientific advances since 2001’s Fourth Edition, especially in computational chemistryCompanion Websites provide digital models for students and exercise solutions for instructors

Descriere

Since its original appearance in 1977, Advanced Organic Chemistry has maintained its place as the premier textbook in the field, offering broad coverage of the structure, reactivity and synthesis of organic compounds. As in the earlier editions, the text contains extensive references to both the primary and review literature and provides examples of data and reactions that illustrate and document the generalizations. While the text assumes completion of an introductory course in organic chemistry, it reviews the fundamental concepts for each topic that is discussed.
The two-part fifth edition has been substantially revised and reorganized for greater clarity. Among the changes: Updated material reflecting advances in the field since 2001’s Fourth Edition, especially in computational chemistry; A companion Web site provides digital models for study of structure, reaction and selectivity; Solutions to the exercises provided to instructors online.
The control of reactivity to achieve specific syntheses is one of the overarching goals of organic chemistry. Part B describes the most general and useful synthetic reactions, organized on the basis of reaction type. Together with Part A: Structure and Mechanisms, the two volumes are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a sufficient foundation to comprehend and use the research literature in organic chemistry.

Textul de pe ultima copertă

Since its original appearance in 1977, Advanced Organic Chemistry has maintained its place as the premier textbook in the field, offering broad coverage of the structure, reactivity and synthesis of organic compounds. As in the earlier editions, the text contains extensive references to both the primary and review literature and provides examples of data and reactions that illustrate and document the generalizations. While the text assumes completion of an introductory course in organic chemistry, it reviews the fundamental concepts for each topic that is discussed.
The two-part fifth edition has been substantially revised and reorganized for greater clarity. Part A begins with the fundamental concepts of structure and stereochemistry, and the thermodynamic and kinetic aspects of reactivity. Major reaction types covered include nucleophilic substitution, addition reactions, carbanion and carbonyl chemistry, aromatic substitution, pericyclic reactions, radical reactions, and photochemistry.
Among the changes:
  • Coverage of the importance of computational chemistry in modern organic chemistry, including applications to many specific reactions.
  • Expanded coverage of stereoselectivity and enantioselectivity, including discussion of several examples of enantioselective reagents and catalysts
  • Chapter 10, Concerted Pericyclic Reactions, has been reorganized and now begins with cycloaddition reactions.
  • The treatment of photochemical reactions has been extensively updated to reflect both experimental and computational studies of the transient intermediates involved in photochemical reactions.
  • A companion Web site provides digital models for study of structure, reaction and selectivity. Here students can view and manipulate computational models of reaction paths. These sites also provide exercises based on detailed study of the computational models.
  • Several chapters in Part A conclude with Topics – short excursions into specific topics such as more detailed analysis of polar substituent effects, efforts to formulate substituent effects in terms of density functional theory, or the role of carbocations in petroleum refining
  • Solutions to the chapter problems are provided to instructors online
Advanced Organic Chemistry Part A provides a close look at the structural concepts and mechanistic patterns that are fundamental to organic chemistry. It relates those mechanistic patterns, including relative reactivity and stereochemistry, to underlying structural factors. Understanding these concepts and relationships will allow students to recognize the cohesive patterns of reactivity in organic chemistry. Part A: Structure and Mechanism and Part B: Reaction and Synthesis - taken together - are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a foundation to comprehend and use the research literature in organic chemistry