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Advanced Organic Chemistry de Francis A. Carey

Advanced Organic Chemistry: Advanced Organic Chemistry

Autor Francis A. Carey, Richard J. Sundberg
en Limba Engleză Paperback – 6 sep 2007

Structura și metodologia lucrării Advanced Organic Chemistry sunt concepute pentru a ghida studentul de la fundamentele teoretice către aplicațiile complexe de cercetare. Organizat în două volume complementare, acest curs avansat își bazează progresia pe o ierarhie logică: Partea A se concentrează pe conceptele structurale — stereochimie, conformație și aromaticitate — în timp ce Partea B, detaliată în acest volum, explorează mecanismele de reacție și sinteza. Descoperim aici o metodologie riguroasă care nu se limitează la prezentarea reacțiilor, ci oferă o documentare vastă prin referințe la literatura primară și de specialitate, facilitând tranziția către munca de laborator. Această a cincea ediție aduce o revizuire substanțială față de versiunea din 2001, integrând progresele majore din domeniul chimiei computaționale. Reținem că materialul este calibrat pentru nivelul graduate, presupunând cunoașterea chimiei organice introductive, dar oferind în același timp recapitulări necesare pentru fiecare temă nouă. Cuprinsul relevă o acoperire exhaustivă, de la alchilarea enolaților și utilizarea compușilor organometalici (Grupul I și II), până la reacții care implică metale de tranziție și sinteze în mai mulți pași. Acoperă aceeași arie ca Organic Synthesis de Michael Smith, dar cu o abordare mai profund ancorată în fundamentele mecanice și structurale, spre deosebire de orientarea strict bazată pe reacții a textului lui Smith. Totodată, se distinge de Computational Organic Chemistry prin faptul că menține un echilibru între metodele de calcul și chimia sintetică tradițională, oferind prin site-ul partener modele digitale ce ajută la vizualizarea selectivității reacțiilor. Este, în esență, un instrument de lucru care transformă teoria în capacitate de cercetare aplicată.

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Specificații

ISBN-13: 9780387683546
ISBN-10: 0387683542
Pagini: 1321
Ilustrații: XXX, 1321 p.
Dimensiuni: 255 x 187 x 50 mm
Greutate: 2.35 kg
Ediția:Fifth Edition 2007
Editura: SPRINGER VERLAG NEW YORK INC
Colecția Advanced Organic Chemistry
Seria Advanced Organic Chemistry

Locul publicării:New York, NY, United States

Public țintă

Graduate

De ce să citești această carte

Pentru studenții la masterat sau doctorat în chimie, această lucrare este standardul de referință care face legătura între cursurile de licență și literatura de cercetare. Cititorul câștigă o înțelegere profundă a mecanismelor de reacție și a metodelor moderne de sinteză, beneficiind de resurse digitale pentru vizualizarea structurilor complexe. Este manualul esențial pentru oricine dorește să stăpânească sinteza organică avansată și chimia metalelor de tranziție.

Despre autor

Francis A. Carey este un reputat profesor emerit la University of Virginia, cu o carieră dedicată predării chimiei organice și cercetării în domeniul mecanismelor sintetice. Educat la Drexel University și Penn State, cu stagii postdoctorale la Harvard, Carey a publicat peste patruzeci de lucrări de cercetare. Expertiza sa didactică este reflectată în claritatea cu care Advanced Organic Chemistry prezintă subiecte complexe, autorul fiind recunoscut pentru capacitatea de a sintetiza literatura de specialitate în formate accesibile studenților avansați.

Cuprins

Alkylation of Enolates and Other Carbon Nucleophiles.- Reactions of Carbon Nucleophiles with Carbonyl Compounds.- Functional Group Interconversion by Substitution, Including Protection and Deprotection.- Electrophilic Additions to Carbon-Carbon Multiple Bonds.- Reduction of Carbon-Carbon Multiple Bonds, Carbonyl Groups, and Other Functional Groups.- Concerted Cycloadditions, Unimolecular Rearrangements, and Thermal Eliminations.- Organometallic Compounds of Group I and II Metals.- Reactions Involving Transition Metals.- Carbon-Carbon Bond-Forming Reactions of Compounds of Boron, Silicon, and Tin.- Reactions Involving Carbocations, Carbenes, and Radicals as Reactive Intermediates.- Aromatic Substitution Reactions.- Oxidations.- Multistep Syntheses.

Recenzii

From the reviews of the fifth edition:
"Advanced Organic Chemistry … the well-known textbook for graduate students – has now appeared in a 5th edition. … Carey & Sundberg will be interesting to all students who seek a detailed understanding of organic chemistry, and who wish to refresh and embellish their existing knowledge. On the strength of the scope and quality of the explanations, this pair of texts is recommended for use as the resource of first resort for specific research questions in one’s later career." (www.organische-chemie.ch, January, 2008)

Notă biografică

Francis A. Carey is a native of Pennsylvania, educated in the public schools of Philadelphia, at Drexel University (B.S. in chemistry, 1959), and at Penn State (Ph.D. 1963). Following postdoctoral work at Harvard and military service, he was appointed to the chemistry faculty of the University of Virginia in 1966. Prior to retiring in 2000, he regularly taught the two-semester lecture courses in general chemistry and organic chemistry. With his students, Professor Carey has published over forty research papers in synthetic and mechanistic organic chemistry.

 
Professor Sundberg is primarily engaged in teaching and chemical education. Along with Francis A. Carey he is the author of “Advanced Organic Chemistry. Professor Sundberg is also interested in synthetic methodology in heterocyclic chemistry and is the author of “Indoles” in the Best Synthetic Methods Series (Academic Press, 1996).
 
 

Caracteristici

Parts A and B may stand alone; together, they provide a comprehensive foundation for study in organic chemistryUpdated material reflecting scientific advances since 2001’s Fourth Edition, especially in computational chemistryCompanion Websites provide digital models for students and exercise solutions for instructors

Descriere

Since its original appearance in 1977, Advanced Organic Chemistry has maintained its place as the premier textbook in the field, offering broad coverage of the structure, reactivity and synthesis of organic compounds. As in the earlier editions, the text contains extensive references to both the primary and review literature and provides examples of data and reactions that illustrate and document the generalizations. While the text assumes completion of an introductory course in organic chemistry, it reviews the fundamental concepts for each topic that is discussed.
The two-part fifth edition has been substantially revised and reorganized for greater clarity. Among the changes: Updated material reflecting advances in the field since 2001’s Fourth Edition, especially in computational chemistry; A companion Web site provides digital models for study of structure, reaction and selectivity; Solutions to the exercises provided to instructors online.
The control of reactivity to achieve specific syntheses is one of the overarching goals of organic chemistry. Part B describes the most general and useful synthetic reactions, organized on the basis of reaction type. Together with Part A: Structure and Mechanisms, the two volumes are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a sufficient foundation to comprehend and use the research literature in organic chemistry.

Textul de pe ultima copertă

Since its original appearance in 1977, Advanced Organic Chemistry has maintained its place as the premier textbook in the field, offering broad coverage of the structure, reactivity and synthesis of organic compounds. As in the earlier editions, the text contains extensive references to both the primary and review literature and provides examples of data and reactions that illustrate and document the generalizations. While the text assumes completion of an introductory course in organic chemistry, it reviews the fundamental concepts for each topic that is discussed.
The two-part fifth edition has been substantially revised and reorganized for greater clarity. Part A begins with the fundamental concepts of structure and stereochemistry, and the thermodynamic and kinetic aspects of reactivity. Major reaction types covered include nucleophilic substitution, addition reactions, carbanion and carbonyl chemistry, aromatic substitution, pericyclic reactions, radical reactions, and photochemistry.
Among the changes:
  • Coverage of the importance of computational chemistry in modern organic chemistry, including applications to many specific reactions.
  • Expanded coverage of stereoselectivity and enantioselectivity, including discussion of several examples of enantioselective reagents and catalysts
  • Chapter 10, Concerted Pericyclic Reactions, has been reorganized and now begins with cycloaddition reactions.
  • The treatment of photochemical reactions has been extensively updated to reflect both experimental and computational studies of the transient intermediates involved in photochemical reactions.
  • A companion Web site provides digital models for study of structure, reaction and selectivity. Here students can view and manipulate computational models of reaction paths. These sites also provide exercises based on detailed study of the computational models.
  • Several chapters in Part A conclude with Topics – short excursions into specific topics such as more detailed analysis of polar substituent effects, efforts to formulate substituent effects in terms of density functional theory, or the role of carbocations in petroleum refining
  • Solutions to the chapter problems are provided to instructors online
Advanced Organic Chemistry Part A provides a close look at the structural concepts and mechanistic patterns that are fundamental to organic chemistry. It relates those mechanistic patterns, including relative reactivity and stereochemistry, to underlying structural factors. Understanding these concepts and relationships will allow students to recognize the cohesive patterns of reactivity in organic chemistry. Part A: Structure and Mechanism and Part B: Reaction and Synthesis - taken together - are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a foundation to comprehend and use the research literature in organic chemistry