In this book, the authors present topical research on new developments in radical polymerization. Topics discussed include interface radical reactions of functional polyperoxides for fabrication of three-dimensional polymeric structures; biomacromolecules in radical processes; nitroxide-mediated photo controlled/living radical polymerisation; alkaline anion-exchange membranes prepared by plasma polymerisation; advancements in controlled radical polymerisation for functional polymers and thermal redox and photoinduced ring opening polymerisation reactions.