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Advanced Molecular Magnetism

Autor Roman Boca
en Limba Engleză Paperback – 2 apr 2026
Advanced Molecular Magnetism provides a rigorous overview of the magnetic properties of molecular and extended inorganic systems. Sections cover the fundamentals of magnetic data recording and analysis, establishing exchange interactions as a foundational concept, including discussions on exchange interactions involving both d- and f-block elements, the role of magnetic anisotropy, single-molecule magnets, and spin crossover phenomena. Content emphasizes the correlation of magnetic property analysis with complementary techniques such as UV-Vis and electron paramagnetic resonance (EPR) spectroscopy. In addition, the book provides a thorough overview of electronic energy levels in transition metal complexes is provided, covering electronic terms, multiplets, and Zeeman splitting.

The interface between quantum mechanics and macroscopic thermodynamic properties is explored through statistical thermodynamics, and the book reviews the major types of magnetic materials—diamagnetic, paramagnetic, ferromagnetic, and antiferromagnetic—with a focus on their underlying principles and real-world examples. Methods for deriving magnetochemical formulae for Curie paramagnets, zero-field splitting systems, T- and E-term systems, and pure multiplet systems are clearly presented, alongside practical guidance for magnetic data collection and analysis. Special attention is given to the magnetism of f-elements and the unique properties of single-molecule magnets, as well as to the correct description of many-electron states in both free atoms and those influenced by crystal fields.

  • Outlines the theory and core principles of molecular magnetism using rigorous language
  • Provides an authoritative overview of the field with up-to-date knowledge and structural language from a highly regarded researcher
  • Includes formulas ready for computational programming
  • Offers practical suggestions for magnetic data collection and analysis, laying the groundwork for effective experimentation
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Specificații

ISBN-13: 9780443449840
ISBN-10: 0443449848
Pagini: 656
Dimensiuni: 152 x 229 mm
Greutate: 0.45 kg
Editura: ELSEVIER SCIENCE

Cuprins

  1. Electromagnetic phenomena
  2. Angular momentum
  3. Statistical thermodynamics in magnetism
  4. Energy levels in many-electron atoms
  5. Energy levels in the crystal field
  6. Zeeman effect
  7. Types of magnetism
  8. Magnetic data taking and analysis
  9. Magnetism of mononuclear complexes
  10. Exchange interaction
  11. Molecular magnetism
  12. Quantum-chemical calculations
  13. Worked examples
  14. Magnetostructural correlations