The Organometallic Chemistry of N–heterocyclic Carbenes (Inorganic Chemistry: A Textbook Series)

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en Limba Engleză Carte Hardback – 31 Mar 2017

The Organometallic Chemistry of N-heterocyclic Carbenes describes various aspects of N-heterocyclic Carbenes (NHCs) and their transition metal complexes at an entry level suitable for advanced undergraduate students and above.

The book starts with a historical overview on the quest for carbenes and their complexes. Subsequently, unique properties, reactivities and nomenclature of the four classical NHCs derived from imidazoline, imidazole, benzimidazole and 1,2,4-triazole are elaborated. General and historically relevant synthetic aspects for NHCs, their precursors and complexes are then explained. The book continues with coverage on the preparation and characteristics of selected NHC complexes containing the most common metals in this area, i.e. Ni, Pd, Pt, Ag, Cu, Au, Ru, Rh and Ir. The book concludes with an overview and outlook on the development of various non-classical NHCs beyond the four classical types.

Topics covered include:

  • Stabilization, dimerization and decomposition of NHCs
  • Stereoelectronic properties of NHCs and their evaluation
  • Diversity of NHCs
  • Isomers of NHC complexes and their identification
  • NMR spectroscopic signatures of NHC complexes
  • normal, abnormal and mesoionic NHCs

The Organometallic Chemistry of N-heterocyclic Carbenes is an essential resource for all students and researchers interested in this increasingly important and popular field of research.

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ISBN-13: 9781118593776
ISBN-10: 1118593774
Pagini: 368
Dimensiuni: 188 x 251 x 22 mm
Greutate: 0.74 kg
Editura: Wiley
Seria Inorganic Chemistry: A Textbook Series

Locul publicării: Chichester, United Kingdom

Public țintă

 Primary market: Final year undergraduate students, graduate students and scientists working in the field of transition metal catalysis and N–heterocyclic carbenes, either in their research or as part of classes dealing with organometallic chemistry and catalysis.
 Secondary Market: Chemists in academia and industry, in particular those working in organic synthesis, organometallic chemistry and catalysis, who would like to learn more about NHCs and/or their complexes.